Thermal Decomposition of Solids and Melts : New Thermochemical Approach to the Mechanism, Kinetics and Methodology / by Boris V. L'vov.

Springer eBooks

Thermal Decomposition: Basic Concepts -- Historical Overview -- Decomposition Mechanism -- Decomposition Kinetics -- Methodology -- Interpretation and Quantitative Analysis of the Effects and Phenomena Accompanying Thermal Decomposition -- Decomposition Conditions and the Molar Enthalpy -- The Self-cooling Effect -- The Topley–Smith Effect -- Impact of Vapour Condensation on the Reaction Enthalpy -- Thermochemical Analysis of the Composition of the Primary Products -- Effect of the Reactant Crystal Structure on the Composition of the Primary Decomposition Products -- Vaporization Coefficients -- The Kinetic Compensation Effect -- Conclusions -- Thermal Decomposition of Individual Substances -- Instruments for Thermogravimetric Measurements -- Measurement Conditions and Procedures for Isothermal Thermogravimetric Studies -- Sublimation and Decomposition Reactions -- Final Remarks.

Thermal Decomposition of Solids and Melts describes the results of investigations into the mechanisms and kinetics involved in the thermal decomposition of solid and liquid substances via thermochemical analysis (TA). The main features of these thermal decomposition reactions are explained within and the observed anomalies are interpreted. New methods of TA measurement and calculation have been developed, which permit the precision and accuracy of determination of kinetic parameters to be increased substantially. Reliable kinetic characteristics have been obtained and the decomposition mechanisms for several substances have been interpreted. These include different classes of compounds: crystalline hydrates oxides hydroxides nitrides azides nitrates sulfates carbonates oxalates This book is intended for advanced undergraduates, researchers, and technologists working in the fields of engineering, metallurgy, chemistry, and material science.

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