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008			150903s2005 xxu| o |||| 0|eng d
020			_a9780387259727 _9978-0-387-25972-7
024	7		_a10.1007/b136380 _2doi
035			_avtls000330229
039		9	_a201509031113 _bVLOAD _c201405070503 _dVLOAD _c201401311333 _dstaff _c201401311158 _dstaff _y201401291450 _zstaff _wmsplit0.mrc _x649
050		4	_aQD505
100	1		_aVannice, M. Albert. _eautor _9302107
245	1	0	_aKinetics of Catalytic Reactions / _cby M. Albert Vannice.
264		1	_aBoston, MA : _bSpringer US, _c2005.
300			_brecurso en línea.
336			_atexto _btxt _2rdacontent
337			_acomputadora _bc _2rdamedia
338			_arecurso en línea _bcr _2rdacarrier
347			_aarchivo de texto _bPDF _2rda
500			_aSpringer eBooks
505	0		_aDefinitions and Concepts -- Catalyst Characterization -- Acquisition and Evaluation of Reaction Rate Data -- Adsorption and Desorption Processes -- Kinetic Data Analysis and Evaluation of Model Parameters for Uniform (Ideal) Surfaces -- Modeling Reactions on Uniform (Ideal) Surfaces -- Modeling Reactions on Nonuniform (Nonideal) Surfaces -- Kinetics of Enzyme-Catalyzed Reactions.
520			_aThis textbook contains all the information needed for graduate students or industrial researchers to design kinetic experiments involving heterogeneous catalysts, to characterize these catalysts, to acquire valid rate data, to verify the absence of mass (and heat) transfer limitations, to propose reaction models, to derive rate expressions based on these models and, finally, to assess the consistency of these rate equations. Langmuir, Freundlich, and Temkin isotherms are derived and the former are used in Langmuir-Hinshelwood (and Hougen-Watson) models, as well as reaction sequences without a rate-determining step, to obtain rate expressions on uniform surfaces. In addition, rate equations based on non-uniform (Temkin-type) surfaces are examined as an alternative approach. The most recent technique to calculate heats of adsorption and activation barriers on metal surfaces, the BOC-MP approach, is discussed in detail. Methods to measure metal surface areas and crystallite sizes using x-ray diffraction, transmission electron microscopy and various chemisorption techniques are discussed. Different experimental techniques to determine the influence of mass transfer limitations, especially within the pores of a catalyst, are reviewed in detail, with a particular emphasis on liquid-phase reactions. Many illustrations of these and other topics are provided along with numerous problems and a Solutions Manual for instructors. This book will be applicable to any graduate course in chemical engineering, chemistry or materials science that involves kinetics of catalytic reactions, including those catalyzed by enzymes.
590			_aPara consulta fuera de la UANL se requiere clave de acceso remoto.
710	2		_aSpringerLink (Servicio en línea) _9299170
776	0	8	_iEdición impresa: _z9780387246499
856	4	0	_uhttp://remoto.dgb.uanl.mx/login?url=http://dx.doi.org/10.1007/b136380 _zConectar a Springer E-Books (Para consulta externa se requiere previa autentificación en Biblioteca Digital UANL)
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999			_c278457 _d278457