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001			282954
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008			150903s2008 ne | o |||| 0|eng d
020			_a9781402066023 _99781402066023
024	7		_a10.1007/9781402066023 _2doi
035			_avtls000335689
039		9	_a201509030754 _bVLOAD _c201404300305 _dVLOAD _y201402041307 _zstaff
040			_aMX-SnUAN _bspa _cMX-SnUAN _erda
050		4	_aQD601-607
100	1		_aZvára, Ivo. _eautor _9310113
245	1	4	_aThe Inorganic Radiochemistry of Heavy Elements : _bMethods for Studying Gaseous Compounds / _cby Ivo Zvára.
264		1	_aDordrecht : _bSpringer Netherlands, _c2008.
300			_brecurso en línea.
336			_atexto _btxt _2rdacontent
337			_acomputadora _bc _2rdamedia
338			_arecurso en línea _bcr _2rdacarrier
347			_aarchivo de texto _bPDF _2rda
500			_aSpringer eBooks
505	0		_aExperimental developments in inorganic gas phase radiochemistry: Early gas–solid chromatography studies -- Techniques for isolation of short-lived accelerator produced activities -- Techniques for alpha-active nuclides with corrosive reagents -- Recent techniques for alpha-active nuclides in non corrosive environment -- Future of radiochemistry studies of heavy metals -- Physicochemical Fundamentals: Molecular kinetics -- Diffusional deposition of molecules and aerosols in channels -- Statistical thermodynamics of adsorption -- Production of transactinoid elements, synthesis and transportation of their compounds: Production of TAE in heavy ion induced reactions -- Synthesis of volatile compounds -- Scavenging of impurities in the gas -- Deposition of nonvolatile elements and compounds from gas flow -- Aerosol stream for transportation of molecular entities -- From gas-solid isothermal chromatography to thermochromatography: General considerations -- Theory -- Simulation of IC and TC peak shape and position -- Vacuum thermochromatography -- Evaluation and interpretation of experimental data: Evaluation of desorption energy / enthalpy from the experimental data -- Experimental adsorption enthalpies of heavy element compounds -- True structure of the column surfaces -- Analysis of poor-statistics data.
520			_aThe aim of this book is to facilitate the wider use of advantageous gas phase techniques towards heavy elements. Studies of the transactinoid elements (polyvalent metals) stimulated application of their volatile halides, oxides, and oxyhalides to fast radiochemical separations. Selected results are presented here. Primarily, this book features the physico-chemical basis of experimental methods and techniques. It focuses on evaluation of the desorption energy from data of a single gas-solid chromatography experiment through calculation of desorption entropy. Heterogeneity of the column surface and its chemical modification are taken into account. Several approaches to the estimation of bulk properties of the compounds from experiments with only a few atoms are also discussed. The accuracy of the derived quantities is then analyzed using the Bayesian statistical approach. The book is aimed at newcomers to the field as well as experts actively engaged in this area of research.
590			_aPara consulta fuera de la UANL se requiere clave de acceso remoto.
710	2		_aSpringerLink (Servicio en línea) _9299170
776	0	8	_iEdición impresa: _z9781402066016
856	4	0	_uhttp://remoto.dgb.uanl.mx/login?url=http://dx.doi.org/10.1007/978-1-4020-6602-3 _zConectar a Springer E-Books (Para consulta externa se requiere previa autentificación en Biblioteca Digital UANL)
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999			_c282954 _d282954