000 03713nam a22003615i 4500
001 282954
003 MX-SnUAN
005 20160429154213.0
007 cr nn 008mamaa
008 150903s2008 ne | o |||| 0|eng d
020 _a9781402066023
_99781402066023
024 7 _a10.1007/9781402066023
_2doi
035 _avtls000335689
039 9 _a201509030754
_bVLOAD
_c201404300305
_dVLOAD
_y201402041307
_zstaff
040 _aMX-SnUAN
_bspa
_cMX-SnUAN
_erda
050 4 _aQD601-607
100 1 _aZvára, Ivo.
_eautor
_9310113
245 1 4 _aThe Inorganic Radiochemistry of Heavy Elements :
_bMethods for Studying Gaseous Compounds /
_cby Ivo Zvára.
264 1 _aDordrecht :
_bSpringer Netherlands,
_c2008.
300 _brecurso en línea.
336 _atexto
_btxt
_2rdacontent
337 _acomputadora
_bc
_2rdamedia
338 _arecurso en línea
_bcr
_2rdacarrier
347 _aarchivo de texto
_bPDF
_2rda
500 _aSpringer eBooks
505 0 _aExperimental developments in inorganic gas phase radiochemistry: Early gas–solid chromatography studies -- Techniques for isolation of short-lived accelerator produced activities -- Techniques for alpha-active nuclides with corrosive reagents -- Recent techniques for alpha-active nuclides in non corrosive environment -- Future of radiochemistry studies of heavy metals -- Physicochemical Fundamentals: Molecular kinetics -- Diffusional deposition of molecules and aerosols in channels -- Statistical thermodynamics of adsorption -- Production of transactinoid elements, synthesis and transportation of their compounds: Production of TAE in heavy ion induced reactions -- Synthesis of volatile compounds -- Scavenging of impurities in the gas -- Deposition of nonvolatile elements and compounds from gas flow -- Aerosol stream for transportation of molecular entities -- From gas-solid isothermal chromatography to thermochromatography: General considerations -- Theory -- Simulation of IC and TC peak shape and position -- Vacuum thermochromatography -- Evaluation and interpretation of experimental data: Evaluation of desorption energy / enthalpy from the experimental data -- Experimental adsorption enthalpies of heavy element compounds -- True structure of the column surfaces -- Analysis of poor-statistics data.
520 _aThe aim of this book is to facilitate the wider use of advantageous gas phase techniques towards heavy elements. Studies of the transactinoid elements (polyvalent metals) stimulated application of their volatile halides, oxides, and oxyhalides to fast radiochemical separations. Selected results are presented here. Primarily, this book features the physico-chemical basis of experimental methods and techniques. It focuses on evaluation of the desorption energy from data of a single gas-solid chromatography experiment through calculation of desorption entropy. Heterogeneity of the column surface and its chemical modification are taken into account. Several approaches to the estimation of bulk properties of the compounds from experiments with only a few atoms are also discussed. The accuracy of the derived quantities is then analyzed using the Bayesian statistical approach. The book is aimed at newcomers to the field as well as experts actively engaged in this area of research.
590 _aPara consulta fuera de la UANL se requiere clave de acceso remoto.
710 2 _aSpringerLink (Servicio en línea)
_9299170
776 0 8 _iEdición impresa:
_z9781402066016
856 4 0 _uhttp://remoto.dgb.uanl.mx/login?url=http://dx.doi.org/10.1007/978-1-4020-6602-3
_zConectar a Springer E-Books (Para consulta externa se requiere previa autentificación en Biblioteca Digital UANL)
942 _c14
999 _c282954
_d282954