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008			150903s2011 ne | o |||| 0|eng d
020			_a9789048128662 _99789048128662
024	7		_a10.1007/9789048128662 _2doi
035			_avtls000365179
039		9	_a201509030710 _bVLOAD _c201405070408 _dVLOAD _y201402211246 _zstaff
040			_aMX-SnUAN _bspa _cMX-SnUAN _erda
050		4	_aQD410-412.5
100	1		_aCazin, Catherine S.J. _eeditor. _9351385
245	1	0	_aN-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis / _cedited by Catherine S.J. Cazin.
264		1	_aDordrecht : _bSpringer Netherlands : _bImprint: Springer, _c2011.
300			_axvI, 340 páginas _brecurso en línea.
336			_atexto _btxt _2rdacontent
337			_acomputadora _bc _2rdamedia
338			_arecurso en línea _bcr _2rdacarrier
347			_aarchivo de texto _bPDF _2rda
490	0		_aCatalysis by Metal Complexes, _x0920-4652 ; _v32
500			_aSpringer eBooks
505	0		_a1. N-Heterocyclic Carbenes – An Introductory Overview -- 2. N-Heterocyclic Carbene Complexes in Additions to Multiple Bonds -- 3. N-Heterocyclic Carbene Complexes in Olefin Metathesis -- 4. N-Heterocyclic Carbene Complexes in Polymerisation, Oligomerisation and Telomerisation Reactions -- 5. N-Heterocyclic Carbene Complexes in Cyclisation Reactions -- 6. N-Heterocyclic Carbene Complexes in Cross-Coupling Reactions -- 7. N-Heterocyclic Carbene Complexes in Arylation Reactions Other than Cross-Couplings -- 8. N-Heterocyclic Carbene Complexes in Dehalogenation Reactions -- 9. N-Heterocyclic Carbene Complexes in Reactions Involving Carbon Monoxide -- 11. N-Heterocyclic Carbene Complexes in Other Transition Metal Mediated Reactions -- 12. N-Heterocyclic Carbenes in Organocatalysis -- 13. N-Heterocyclic Carbene Complexes - Decomposition Pathways -- 14. N-Heterocyclic Carbene Complexes in Industrial Processes.
520			_aN-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, … Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.
590			_aPara consulta fuera de la UANL se requiere clave de acceso remoto.
710	2		_aSpringerLink (Servicio en línea) _9299170
776	0	8	_iEdición impresa: _z9789048128655
856	4	0	_uhttp://remoto.dgb.uanl.mx/login?url=http://dx.doi.org/10.1007/978-90-481-2866-2 _zConectar a Springer E-Books (Para consulta externa se requiere previa autentificación en Biblioteca Digital UANL)
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