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020 _a9789048136988
_99789048136988
024 7 _a10.1007/9789048136988
_2doi
035 _avtls000365428
039 9 _a201509031055
_bVLOAD
_c201405070413
_dVLOAD
_y201402211252
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040 _aMX-SnUAN
_bspa
_cMX-SnUAN
_erda
050 4 _aQD415-436
100 1 _aPérez, Pedro J.
_eeditor.
_9355270
245 1 0 _aAlkane C-H Activation by Single-Site Metal Catalysis /
_cedited by Pedro J. Pérez.
264 1 _aDordrecht :
_bSpringer Netherlands :
_bImprint: Springer,
_c2012.
300 _axiv, 269 páginas 272 ilustraciones
_brecurso en línea.
336 _atexto
_btxt
_2rdacontent
337 _acomputadora
_bc
_2rdamedia
338 _arecurso en línea
_bcr
_2rdacarrier
347 _aarchivo de texto
_bPDF
_2rda
490 0 _aCatalysis by Metal Complexes,
_x0920-4652 ;
_v38
500 _aSpringer eBooks
505 0 _aForeword by Robert G. Bergman -- Introduction: Alkane C—H Activation by Single-Site Metal Catalysis -- Alkane Functionalization via Electrophilic Activation -- Catalytic Carbon–Boron Bond Formation via Activation of Alkane C–H Bonds -- Alkane Dehydrogenation -- Alkane C-H Oxygenation Catalyzed by Transition Metal Complexes -- Alkane Catalytic Functionalization by Carbene or Nitrene Insertion Reactions.
520 _aOver the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C?H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system.  Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.
590 _aPara consulta fuera de la UANL se requiere clave de acceso remoto.
710 2 _aSpringerLink (Servicio en línea)
_9299170
776 0 8 _iEdición impresa:
_z9789048136971
856 4 0 _uhttp://remoto.dgb.uanl.mx/login?url=http://dx.doi.org/10.1007/978-90-481-3698-8
_zConectar a Springer E-Books (Para consulta externa se requiere previa autentificación en Biblioteca Digital UANL)
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999 _c313163
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